Write Lewis symbols for the following atoms and ions:
S and S2–; Al and Al3+; H and H–
(i) S and S2– Electronic configuration of S is [Ne]10 3s23p4, i.e it has 6 electrons in its valence shell,therefore The Lewis dot symbol of sulphur (S) is . The dinegative charge shows that there will be two electrons more in addition to the six valence electrons. The electronic configuration can be [Ne]10 3s23p6, Hence, the Lewis dot symbol of S2– is
.
(ii) Al and Al3+ The electronic configuration of Aluminium is [Ne]10 3s2 3p1, i.e the valence electron is 3,therefore The Lewis dot symbol of aluminium (Al) is . The tripositive charge on a species infers that it has donated its three electrons to other atom & its possible electronic configuration is [Ne]10 3s1. Hence, the Lewis dot symbol is
.
(iii) H and H– Hydrogen has electronic configuration of 1s1,it has 1 electron in its valence shell. The Lewis dot symbol of hydrogen (H) is . The uninegative charge infers that there will be one electron more in addition to the one valence electron. The possible configuration may be 1s2. Hence, the Lewis dot symbol is
.
What is meant by the term bond order? Calculate the bond order of: N2, O2,O2+,and O2-.
Use molecular orbital theory to explain why the Be2 molecule does not exist.
Explain the formation of H2 molecule on the basis of valence bond theory.
Compare the relative stability of the following species and indicate their magnetic properties:
O2,O2+,O2- (superoxide), O22-(peroxide)
Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?
Which out of NH3 and NF3 has higher dipole moment and why?
Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3, SiCl4, AsF5, H2S, PH3
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
Describe the change in hybridisation (if any) of the Al atom in the following reaction.
Draw the Lewis structures for the following molecules and ions: H2S, SiCl4, BeF2, , HCOOH
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
How much energy is required to ionise a H atom if the electron occupies n = 5 orbit? Compare your answer with the ionization enthalpy of H atom (energy required to remove the electron from n =1 orbit).
Use the periodic table to answer the following questions.
(a) Identify an element with five electrons in the outer subshell.
(b) Identify an element that would tend to lose two electrons.
(c) Identify an element that would tend to gain two electrons.
(d) Identify the group having metal, non-metal, liquid as well as gas at the room temperature.
(i) Calculate the total number of electrons present in one mole of methane.
(ii) Find
(a) the total number and
(b) the total mass of neutrons in 7 mg of 14C. (Assume that mass of a neutron = 1.675 × 10–27 kg).
(iii) Find
(a) the total number and
(b) the total mass of protons in 34 mg of NH3 at STP.
Will the answer change if the temperature and pressure are chang
Show that the circumference of the Bohr orbit for the hydrogen atom is an integral multiple of the de Broglie wavelength associated with the electron revolving around the orbit.
An ion with mass number 56 contains 3 units of positive charge and 30.4% more neutrons than electrons. Assign the symbol to this ion.
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
One of the reaction that takes place in producing steel from iron ore is the reduction of iron(II) oxide by carbon monoxide to give iron metal and CO2.
FeO (s) + CO (g) ↔ Fe (s) + CO2 (g); Kp = 0.265 atm at 1050K
What are the equilibrium partial pressures of CO and CO2 at 1050 K if the initial partial pressures are: pCO= 1.4 atm and Pco2 = 0.80 atm
Give the number of electrons in the species , H2 and
Consider the reaction of water with F2 and suggest, in terms of oxidation and reduction, which species are oxidised or reduced.
An electron is in one of the 3d orbitals. Give the possible values of n, l and ml for this electron.
Better answers for my questions you gave me
Nice ans it give with explanation
It is. Very use full for all student
was very helpful. thank you.