Which out of NH3 and NF3 has higher dipole moment and why?
In both molecules i.e., NH3 and NF3, the central atom (N) has a lone pair electron and there are three bond pairs. Hence, both molecules have a pyramidal shape. Since fluorine is more electronegative than hydrogen, it is expected that the net dipole moment of NF3 is greater than NH3. However, the net dipole moment of NH3 (1.46 D) is greater than that of NF3 (0.24 D).
This can be explained on the basis of the directions of the dipole moments of each individual bond in NF3 and NH3.
Since in case of NF3, fluorine is more electronegative than nitrogen, so it will attract the shared pair of electron towards itself from nitrogen. As a result dipole due to all F is in opposite direction to the resultant dipole due to N-F bonds, therefore the net dipole decreases.
In NH3, Nitrogen is more electronegative than H, so it will attract the shared pair of electrons towards itself. As a result dipole due to Nitrogen is in same direction as the resultant dipole moment due to N-H bond and hence the net dipole increases.
Hence, the net dipole moment of NF3 is less than that of NH3.
Popular Questions of Class 11 Chemistry
- Q:-
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
- Q:-
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
- Q:-
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
- Q:-
Balance the following redox reactions by ion – electron method :
(a) MnO4 – (aq) + I – (aq) → MnO2 (s) + I2(s) (in basic medium)
(b) MnO4 – (aq) + SO2 (g) → Mn2+ (aq) + HSO4– (aq) (in acidic solution)
(c) H2O2 (aq) + Fe 2+ (aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d) Cr2O7 2– + SO2(g) → Cr3+ (aq) + SO42– (aq) (in acidic solution)
- Q:-
In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?
- Q:-
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
- Q:-
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
- Q:-
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
- Q:-
Which one of the following will have largest number of atoms?
(i) 1 g Au (s)
(ii) 1 g Na (s)
(iii) 1 g Li (s)
(iv) 1 g of Cl2(g)
- Q:-
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Recently Viewed Questions of Class 11 Chemistry
- Q:-
Write the resonance structures for SO3, NO2 and
. - Q:-
Describe the importance of the following: (i) limestone (ii) cement (iii) plaster of paris.
- Q:-
Calculate the mass of sodium acetate (CH3COONa) required to make 500 mL of 0.375 molar aqueous solution. Molar mass of sodium acetate is 82.0245 g mol–1
- Q:-
How does atomic radius vary in a period and in a group? How do you explain the variation?
- Q:-
Write the complete symbol for the atom with the given atomic number (Z) and Atomic mass (A)
(i) Z = 17, A = 35
(ii) Z = 92, A = 233
(iii) Z = 4, A = 9
- Q:-
Why does hydrogen occur in a diatomic form rather than in a monoatomic form under normal conditions?
- Q:-
Which of the following pairs of elements would have a more negative electron gain enthalpy?
(i) O or F
(ii) F or Cl - Q:-
Write balanced equations for:
(i) BF3 + LiH →
(ii) B2H6 + H2O →
(iii) NaH + B2H6 →
(iv) H3BO3
(v) Al + NaOH →
(vi) B2H6 + NH3 →
- Q:-
How much copper can be obtained from 100 g of copper sulphate (CuSO4)?
- Q:-
The velocity associated with a proton moving in a potential difference of 1000 V is 4.37 × 105 ms–1. If the hockey ball of mass 0.1 kg is moving with this velocity, calculate the wavelength associated with this velocity.
2 Comment(s) on this Question
not bad
Yo
- NCERT Chapter