What do you understand by the term glycosidic linkage?
Glycosidic linkage refers to the linkage formed between two monosaccharide units through an oxygen atom by the loss of a water molecule.
For example, in a sucrose molecule, two monosaccharide units, ∝-glucose and β-fructose, are joined together by a glycosidic linkage.
What happens when D-glucose is treated with the following reagents? (i)HI (ii)Bromine water (iii)HNO3
How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain.
Define the following as related to proteins
(i) Peptide linkage (ii) Primary structure (iii) Denaturation.
What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?
The two strands in DNA are not identical but are complementary. Explain.
What are nucleic acids? Mention their two important functions.
Enumerate the reactions of D-glucose which cannot be explained by its open chain structure.
Where does the water present in the egg go after boiling the egg?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
Low level of noradrenaline is the cause of depression. What type of drugs are needed to cure this problem ? Name two drugs.
Describe a method for refining nickel.
Discuss the main purpose of vulcanisation of rubber.
Complete the following acid-base reactions and name the products:
(i) CH3CH2CH2NH2 + HCl →
(ii) (C2H5)3N + HCl →
Write balanced equations for the following:
(i) NaCl is heated with sulphuric acid in the presence of MnO2.
(ii) Chlorine gas is passed into a solution of NaI in water.
Describe some features of catalysis by zeolites.
Write the name and structure of one of the common initiators used in free radical addition polymerisation.
Arrange the following:
(i) In decreasing order of the pKbvalues:
C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NH2
(ii) In increasing order of basic strength:
C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2
(iii) In increasing order of basic strength:
(a) Aniline, p-nitroaniline and p-toluidine
(b) C6H5NH2, C6H5NHCH3, C6H5CH2NH2.
(iv) In decreasing order of basic strength in gas phase:
C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3
(v) In increasing order of boiling point:
C2H5OH, (CH3)2NH, C2H5NH2
(vi) In increasing order of solubility in water:
C6H5NH2, (C2H5)2NH, C2H5NH2.
How are colloids classified on the basis of
(i) Physical states of components
(ii) Nature of dispersion medium and
(iii) Interaction between dispersed phase and dispersion medium?