Define hydrogen bond. Is it weaker or stronger than the van der Waals forces?
A hydrogen bond represents a dipolar attraction between hydrogen atom and highly electronegative atom. The hydrogen bond is represented by ----------(dotted lines).
For example: H -----------X -----------X -------- X------
X = O, N, S, F, Cl….
The bond pair involved in hydrogen bonding was attracted more towards highly electronegative atom, as a result H atom will start acquiring a partial positive charge (δ+) and the electronegative atom will acquire a partial negative charge (δ-).
The magnitude of H-bonding is maximum in the solid state and minimum in the gaseous state.
Hydrogen bonds are of two types
(i) Intermolecular H-bond e.g., HF, H2O etc.
(ii) Intramolecular H-bond e.g., o-nitrophenol
Vander waal’s forces are weak forces and exist in non -polar compounds and noble gases .As compared to hydrogen bonds they are weak in nature because of strong dipole -dipole interaction in hydrogen bonding.
What is meant by the term bond order? Calculate the bond order of: N2, O2,O2+,and O2-.
Use molecular orbital theory to explain why the Be2 molecule does not exist.
Explain the formation of H2 molecule on the basis of valence bond theory.
Compare the relative stability of the following species and indicate their magnetic properties:
O2,O2+,O2- (superoxide), O22-(peroxide)
Describe the hybridisation in case of PCl5. Why are the axial bonds longer as compared to equatorial bonds?
Which out of NH3 and NF3 has higher dipole moment and why?
Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3, SiCl4, AsF5, H2S, PH3
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
Write Lewis symbols for the following atoms and ions:
S and S2–; Al and Al3+; H and H–
Describe the change in hybridisation (if any) of the Al atom in the following reaction.
How do you account for the formation of ethane during chlorination of methane?
What are hybridisation states of each carbon atom in the following compounds ?
(i) CH2=C=O,
(ii) CH3CH=CH2,
(iii) (CH3)2CO,
(iv) CH2=CHCN,
(v) C6H6
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
What are the common physical and chemical features of alkali metals?
Calculate the molecular mass of the following:
(i) H2O
(ii) CO2
(iii) CH4
Assign oxidation number to the underlined elements in each of the following species:
(a) NaH2PO4
(b) NaHSO4
(c) H4P2O7
(d) K2MnO4
(e) CaO2
(f) NaBH4
(g) H2S2O7
(h) KAl(SO4)2.12 H2O
What is the basic theme of organisation in the periodic table?
Choose the correct answer. A thermodynamic state function is a quantity
(i) used to determine heat changes
(ii) whose value is independent of path
(iii) used to determine pressure volume work
(iv) whose value depends on temperature only.
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
a) What is the initial effect of the change on vapour pressure?
b) How do rates of evaporation and condensation change initially?
c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.
Find the oxidation state of sodium in Na2O2.
State as to why
(a) a solution of Na2CO3 is alkaline ?
(b) alkali metals are prepared by electrolysis of their fused chlorides ?
(c) sodium is found to be more useful than potassium ?
Calculate the mass percent of different elements present in sodium sulphate (Na2SO4).
The pH of 0.1M solution of cyanic acid (HCNO) is 2.34. Calculate the ionization constant of the acid and its degree of ionization in the solution.
Which of the followings are Lewis acids? H2O, BF3, H+ and NH+4
Is boric acid a protic acid? Explain.
Indicate the σ and π bonds in the following molecules :
(i) C6H6,
(ii) C6H12,
(iii) CH2Cl2,
(iv) CH2=C=CH2,
(v) CH3NO2,
(vi) HCONHCH3
Give the IUPAC names of the following compounds:
An element with mass number 81 contains 31.7% more neutrons as compared to protons. Assign the atomic symbol.
Why are alkali metals not found in nature?
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