Class 12 Chemistry - Chapter Coordination Compounds NCERT Solutions | Discuss briefly giving an example in eac
Discuss briefly giving an example in each case the role of coordination compounds in:
(i) biological system
(ii) medicinal chemistry
(iii) analytical chemistry
(iv) extraction/metallurgy of metals
(i) Role of coordination compounds in biological systems:
We know that photosynthesis is made possible by the presence of the chlorophyll pigment. This pigment is a coordination compound of magnesium. In the human biological system, several coordination compounds play important roles. For example, the oxygen-carrier of blood, i.e., haemoglobin, is a coordination compound of iron.
(ii) Role of coordination compounds in medicinal chemistry:
Certain coordination compounds of platinum (for example, cis- platin) are used for inhibiting the growth of tumours.
(iii) Role of coordination compounds in analytical chemistry:
During salt analysis, a number of basic radicals are detected with the help of the colour changes they exhibit with different reagents. These colour changes are a result of the coordination compounds or complexes that the basic radicals form with different ligands.
(iv) Role of coordination compounds in extraction or metallurgy of metals:
The process of extraction of some of the metals from their ores involves the formation of complexes. For example, in aqueous solution, gold combines with cyanide ions to form [Au(CN)2]. From this solution, gold is later extracted by the addition of zinc metal.
More Questions From Class 12 Chemistry - Chapter Coordination Compounds
- Q:-
[NiCl4]2- is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why?
- Q:-
Explain on the basis of valence bond theory that [Ni(CN)4]2- ion with square planar structure is diamagnetic and the [Ni(CN)4]2- ion with tetrahedral geometry is paramagnetic.
- Q:-
Draw figure to show the splitting of d orbitals in an octahedral crystal field.
- Q:-
Write down the IUPAC name for each of the following complexes and indicate the oxidation state, electronic configuration and coordination number. Also give stereochemistry and magnetic moment of the complex:
(i) K[Cr(H2O)2(C2O4)2].3H2O
(ii) [Co(NH3)5Cl]Cl2
(iii) CrCl3(py)3
(iv) Cs[FeCl4]
(v) K4[Mn(CN)6]
- Q:-
[Cr(NH3)6]3+ is paramagnetic while [Ni(CN)4]2- is diamagnetic. Explain why?
- Q:-
The oxidation number of cobalt in K[Co(CO)4] is
(i) +1
(ii) +3
(iii) -1
(iv) -3
- Q:-
Discuss the nature of bonding in metal carbonyls.
- Q:-
Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
(i) [Fe(CN)6]4-
(ii) [FeF6]3-
(iii) [Co(C2O4)3]3-
(iv) [CoF6]3-
- Q:-
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
- Q:-
Predict the number of unpaired electrons in the square planar [Pt(CN)4]2- ion.
Popular Questions of Class 12 Chemistry
- Q:-
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
- Q:-
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
- Q:-
Why are solids rigid?
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Write any two characteristics of Chemisorption.
- Q:-
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
- Q:-
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
- Q:-
Why are pentahalides more covalent than trihalides?
- Q:-
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
- Q:-
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
- Q:-
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
Recently Viewed Questions of Class 12 Chemistry
- Q:-
Compare the stability of +2 oxidation state for the elements of the first transition series.
- Q:-
An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water. Calculate the molality of the solution. If the density of the solution is 1.072 g mL-1, then what shall be the molarity of the solution?
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Considering the parameters such as bond dissociation enthalpy, electron gain enthalpy and hydration enthalpy, compare the oxidising power of F2 and Cl2.
- Q:-
How the following conversions can be carried out?
(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane
(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane
(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
- Q:-
Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
- Q:-
Bond angle in PH+4 is higher than that in PH3. Why?
- Q:-
Define the term polymerisation.
- Q:-
How will you prepare the following compounds from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom
(i) Methyl benzoate (ii) m-Nitrobenzoic acid
(iii) p-Nitrobenzoic acid (iv) Phenylacetic acid
(v) p-Nitrobenzaldehyde.
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