The reaction,
Cr2O3 + 2Al → Al2O3 + 2Cr (ΔGo = -421kJ)
is thermodynamically feasible as is apparent from the Gibbs energy value. Why does it not take place at room temperature?
The change in Gibbs energy is related to the equilibrium constant, K as
ΔG = - RT in K
At room temperature, all reactants and products of the given reaction are in the solid state. As a result, equilibrium does not exist between the reactants and the products. Hence, the reaction does not take place at room temperature. However, at a higher temperature, chromium melts and the reaction takes place.
We also know that according to the equation,
ΔG = ΔH - TΔS
Increasing the temperature increases the value of TΔS, making the value of ΔG more and more negative. Therefore, the reaction becomes more and more feasible as the temperature is increased.
What is the significance of leaching in the extraction of aluminium?
Write down the reactions taking place in different zones in the blast furnace during the extraction of iron.
Copper can be extracted by hydrometallurgy but not zinc. Explain.
Outline the principles of refining of metals by the following methods:
(i) Zone refining
(ii) Electrolytic refining
(iii) Vapour phase refining
Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present ?
How can you separate alumina from silica in bauxite ore associated with silica? Give equations, if any.
Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?
Write chemical reactions taking place in the extraction of zinc from zinc blende.
Describe a method for refining nickel.
Why copper matte is put in silica lined converter?
For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.
Write the formulas for the following coordination compounds:
(i) Tetraamminediaquacobalt (III) chloride
(ii) Potassium tetracyanonickelate(II)
(iii) Tris(ethane-1,2-diamine) chromium(III) chloride
(iv) Amminebromidochloridonitrito-N-platinate(II)
(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate
(vi) Iron(III) hexacyanoferrate(II)
(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N
(ii) Write IUPAC names of all the isomers.
(iii) What type of isomerism is exhibited by different pairs of amines?
Why are solids rigid?
Write any two characteristics of Chemisorption.
Write the structures of the following compounds.
(i) α-Methoxypropionaldehyde
(ii) 3-Hydroxybutanal
(iii) 2-Hydroxycyclopentane carbaldehyde
(iv) 4-Oxopentanal
(v) Di-sec-butyl ketone
(vi) 4-Fluoroacetophenone
Why are pentahalides more covalent than trihalides?
Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?
Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.
Write structures of the following compounds:
(i) 2-Chloro-3-methylpentane
(ii) 1-Chloro-4-ethylcyclohexane
(iii) 4-tert. Butyl-3-iodoheptane
(iv) 1,4-Dibromobut-2-ene
(v) 1-Bromo-4-sec. butyl-2-methylbenzene
What is lanthanoid contraction? What are the consequences of lanthanoid contraction?
Suggest the most important type of intermolecular attractive interaction in the following pairs.
(i) n-hexane and n-octane
(ii) I2 and CCl4
(iii) NaClO4 and water
(iv) methanol and acetone
(v) acetonitrile (CH3CN) and acetone (C3H6O).
A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.
Bond angle in PH+4 is higher than that in PH3. Why?
Give the structures and IUPAC names of monohydric phenols of molecular formula, C7H8O.
Write the reactions of F2 and Cl2 with water.
The decomposition of A into product has value of k as 4.5 x 103 s-1 at 10°C and energy of activation 60 kJ mol-1. At what temperature would k be 1.5 x 104 s-1?
An aromatic compound 'A' on treatment with aqueous ammonia and heating forms compound 'B' which on heating with Br2 and KOH forms a compound 'C' of molecular formula C6H7N. Write the structures and IUPAC names of compounds A, B and C.
How can you differentiate between addition and condensation polymerisation?
How many lattice points are there in one unit cell of each of the following lattice?
(i) Face-centred cubic
(ii) Face-centred tetragonal
(iii) Body-centred