Class 12 Chemistry - Chapter Electrochemistry NCERT Solutions | Three electrolytic cells A,B,C containin

If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?

Calculate the emf of the cell in which the following reaction takes place:

Ni_(s) + 2Ag⁺ (0.002 M) → Ni²⁺ (0.160 M) + 2Ag_(s)

Given that E^ø_cell = 1.05 V

Depict the galvanic cell in which the reaction Zn(s) + 2Ag⁺(aq) → Zn²⁺(aq) + 2Ag(s) takes place.

Further show:

(i) Which of the electrode is negatively charged?

(ii) The carriers of the current in the cell.

(iii) Individual reaction at each electrode.

Calculate the standard cell potentials of galvanic cells in which the following reactions take place:

(i) 2Cr(s) + 3Cd²⁺(aq) → 2Cr³⁺(aq) + 3Cd

(ii) Fe²⁺(aq) + Ag+(aq) → Fe³⁺(aq) + Ag(s)

Calculate the ΔrG^ø¸ and equilibrium constant of the reactions.

Write the Nernst equation and emf of the following cells at 298 K:

(i) Mg(s) | Mg²⁺(0.001M) || Cu²⁺(0.0001 M) | Cu(s)

(ii) Fe(s) | Fe²⁺(0.001M) || H⁺(1M)|H₂(g)(1bar) | Pt(s)

(iii) Sn(s) | Sn²⁺(0.050 M) || H⁺(0.020 M) | H₂(g) (1 bar) | Pt(s)

(iv) Pt(s) | Br₂(l) | Br^-(0.010 M) || H⁺(0.030 M) | H₂(g) (1 bar) | Pt(s).

Define conductivity and molar conductivity for the solution of an electrolyte. Discuss their variation with concentration.

How would you determine the standard electrode potential of the system Mg²⁺ | Mg?

Predict the products of electrolysis in each of the following:

(i) An aqueous solution of AgNO₃ with silver electrodes.

(ii) An aqueous solution of AgNO₃with platinum electrodes.

(iii) A dilute solution of H₂SO₄with platinum electrodes.

(iv) An aqueous solution of CuCl₂ with platinum electrodes.

A solution of Ni(NO₃)₂ is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?

The resistance of a conductivity cell containing 0.001M KCl solution at 298 K is 1500 Ω. What is the cell constant if conductivity of 0.001M KCl solution at 298 K is 0.146 x 10^-3 S cm^-1.

For the reaction R → P, the concentration of a reactant changes from 0.03 M to 0.02 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.

Write the formulas for the following coordination compounds:

(i) Tetraamminediaquacobalt (III) chloride

(ii) Potassium tetracyanonickelate(II)

(iii) Tris(ethane-1,2-diamine) chromium(III) chloride

(iv) Amminebromidochloridonitrito-N-platinate(II)

(v) Dichloridobis(ethane-1,2-diamine)platinum(IV) nitrate

(vi) Iron(III) hexacyanoferrate(II)

(i) Write structures of different isomeric amines corresponding to the molecular formula, C4H11N

(ii) Write IUPAC names of all the isomers.

(iii) What type of isomerism is exhibited by different pairs of amines?

Why are solids rigid?

Write any two characteristics of Chemisorption.

Write the structures of the following compounds.

(i) α-Methoxypropionaldehyde

(ii) 3-Hydroxybutanal

(iii) 2-Hydroxycyclopentane carbaldehyde

(iv) 4-Oxopentanal

(v) Di-sec-butyl ketone

(vi) 4-Fluoroacetophenone

Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?

Why are pentahalides more covalent than trihalides?

Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a transition element?

Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are insoluble in water. Explain.

Where does the water present in the egg go after boiling the egg?

[Fe(CN)₆]^4- and [Fe(H₂O)₆]²⁺ are of different colours in dilute solutions. Why?

Illustrate how copper metal can give different products on reaction with HNO₃.

Why is the ester hydrolysis slow in the beginning and becomes faster after sometime?

How are polymers classified on the basis of structure?

Which acid of each pair shown here would you expect to be stronger?

(i) CH₃CO₂H or CH₂FCO₂H

(ii)CH₂FCO₂H or CH₂ClCO₂H

(iii) CH₂FCH₂CH₂CO₂H or CH₃CHFCH₂CO₂H

(iv)

Give structures of the products you would expect when each of the following alcohol reacts with (a) HCl-ZnCl₂ (b) HBr and (c) SOCl₂.

(i) Butan-1-ol

(ii) 2-Methylbutan-2-ol

A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1.2 g mL^-1, then what shall be the molarity of the solution?

What are the different types of RNA found in the cell?

Predict the major product of acid catalysed dehydration of

(i) 1-Methylcyclohexanol and

(ii) Butan-1-ol