Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
The ideal gas equation relating pressure (P), volume (V), and absolute temperature (T) is given as:
PV= nRT
Where, R is the universal gas constant = 8.314 J mol-1K-1
n= Number of moles = 1
T= Standard temperature = 273 K
P= Standard pressure = 1 atm = 1.013 × 105 Nm-2
∴ V = nRT / P
= 1 x 8.314 x 273 / 1.013 x 105
= 0.0224 m3 = 22.4 litres
Hence, the molar volume of a gas at STP is 22.4 litres.
State the number of significant figures in the following:
(a) 0.007 m2
(b) 2.64 x 1024 kg
(c) 0.2370 g cm-3
(d) 6.320 J
(e) 6.032 N m-2
(f) 0.0006032 m2
Fill in the blanks by suitable conversion of units:
(a) 1 kg m2s–2= ....g cm2 s–2
(b) 1 m =..... ly
(c) 3.0 m s–2=.... km h–2
(d) G = 6.67 × 10–11 N m2 (kg)–2=.... (cm)3s–2 g–1.
A physical quantity P is related to four observables a, b, c and d as follows :
The percentage errors of measurement in a, b, c and d are 1%, 3%, 4% and 2%, respectively. What is the percentage error in the quantity P ? If the value of P calculated using the above relation turns out to be 3.763, to what value should you round off the result ?
Rain is falling vertically with a speed of 30 m s–1. A woman rides a bicycle with a speed of 10 m s–1 in the north to south direction. What is the direction in which she should hold her umbrella?
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
On an open ground, a motorist follows a track that turns to his left by an angle of 60° after every 500 m. Starting from a given turn, specify the displacement of the motorist at the third, sixth and eighth turn. Compare the magnitude of the displacement with the total path length covered by the motorist in each case.
What amount of heat must be supplied to 2.0 x 10-2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N2 = 28; R = 8.3 J mol-1 K-1.)
A transverse harmonic wave on a string is described by
y(x,t) = 3.0 sin [36t + 0.018x + π /4]
Where x and y are in cm and t in s. The positive direction of x is from left to right.
(a) Is this a travelling wave or a stationary wave? If it is travelling, what are the speed and direction of its propagation?
(b) What are its amplitude and frequency?
(c) What is the initial phase at the origin?
(d) What is the least distance between two successive crests in the wave?
Look at the graphs (a) to (d) (Fig. 3.20) carefully and state, with reasons, which of these cannot possibly represent one-dimensional motion of a particle.
(a)
The acceleration due to gravity on the surface of moon is 1.7 ms-2. What is the time period of a simple pendulum on the surface of moon if its time period on the surface of earth is 3.5 s? (g on the surface of earth is 9.8 ms-2)
Use the formula v = √ γP/ρ to explain why the speed of sound in air (a) is independent of pressure, (b) increases with temperature, (c) increases with humidity.
The ceiling of a long hall is 25 m high. What is the maximum horizontal distance that a ball thrown with a speed of 40 m s–1 can go without hitting the ceiling of the hall?
A string of mass 2.50 kg is under a tension of 200 N. The length of the stretched string is 20.0 m. If the transverse jerk is struck at one end of the string, how long does the disturbance take to reach the other end?
The velocity-time graph of a particle in one-dimensional motion is shown in Fig. 3.29:
Which of the following formulae are correct for describing the motion of the particle over the time-interval t2 to t1?
(a) x(t2) = x (t1) + v (t1) (t2–t1) + (1/2) a (t2–t1)2
(b) v(t2)= v(t1) + a(t2–t1)
(c) vAverage = (x(t2) – x (t1)) / (t2 – t1)
(d) aAverage = (v(t2) – v(t1)) / (t2 – t1)
(e) x(t2) = x(t1) + vAverage(t2 – t1) + ( 1/2 ) aAverage (t2–t1)2
(f) x(t2) – x(t1) = area under the v–t curve bounded by the t-axis and the dotted line shown.
A simple pendulum of length l and having a bob of mass M is suspended in a car. The car is moving on a circular track of radius R with a uniform speed v. If the pendulum makes small oscillations in a radial direction about its equilibrium position, what will be its time period?
It is claimed that two cesium clocks, if allowed to run for 100 years, free from any disturbance, may differ by only about 0.02 s. What does this imply for the accuracy of the standard cesium clock in measuring a time-interval of 1 s?
Does it matter if one uses gauge instead of absolute pressures in applying Bernoulli's equation? Explain.