Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
The ideal gas equation relating pressure (P), volume (V), and absolute temperature (T) is given as:
PV= nRT
Where, R is the universal gas constant = 8.314 J mol-1K-1
n= Number of moles = 1
T= Standard temperature = 273 K
P= Standard pressure = 1 atm = 1.013 × 105 Nm-2
∴ V = nRT / P
= 1 x 8.314 x 273 / 1.013 x 105
= 0.0224 m3 = 22.4 litres
Hence, the molar volume of a gas at STP is 22.4 litres.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
The position of a particle is given by
Where t is in seconds and the coefficients have the proper units for r to be in meters.
(a) Find the v and a of the particle?
(b) What is the magnitude and direction of velocity of the particle at t = 2.0 s?
A stone tied to the end of a string 80 cm long is whirled in a horizontal circle with a constant speed. If the stone makes 14 revolutions in 25 s, what is the magnitude and direction of acceleration of the stone?
A monkey of mass 40 kg climbs on a rope (Fig. 5.20) which can stand a maximum tension of 600 N. In which of the following cases will the rope break: the monkey
(a) climbs up with an acceleration of 6 m s-2
(b) climbs down with an acceleration of 4 m s-2
(c) climbs up with a uniform speed of 5 m s-1
(d) falls down the rope nearly freely under gravity?
(Ignore the mass of the rope).
Given a + b + c + d = 0, which of the following statements are correct:
(a) a, b, c, and d must each be a null vector,
(b) The magnitude of (a + c) equals the magnitude of (b+ d),
(c) The magnitude of a can never be greater than the sum of the magnitudes of b, c, and d,
(d) b + c must lie in the plane of a and d if a and d are not collinear, and in the line of a and d, if they are collinear?
Which of the following relationships between the acceleration a and the displacement x of a particle involve simple harmonic motion?
(a) a = 0.7x
(b) a = -200x2
(c) a = -10x
(d) a = 100x3
Torques of equal magnitude are applied to a hollow cylinder and a solid sphere, both having the same mass and radius. The cylinder is free to rotate about its standard axis of symmetry, and the sphere is free to rotate about an axis passing through its centre. Which of the two will acquire a greater angular speed after a given time?
A LASER is a source of very intense, monochromatic, and unidirectional beam of light. These properties of a laser light can be exploited to measure long distances. The distance of the Moon from the Earth has been already determined very precisely using a laser as a source of light. A laser light beamed at the Moon takes 2.56 s to return after reflection at the Moon's surface. How much is the radius of the lunar orbit around the Earth?
A circular disc of mass 10 kg is suspended by a wire attached to its centre. The wire is twisted by rotating the disc and released. The period of torsional oscillations is found to be 1.5 s. The radius of the disc is 15 cm. Determine the torsional spring constant of the wire.
(Torsional spring constant α is defined by the relation J = -α ø, where J is the restoring couple and ø¸ the angle of twist).