Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
The ideal gas equation relating pressure (P), volume (V), and absolute temperature (T) is given as:
PV= nRT
Where, R is the universal gas constant = 8.314 J mol-1K-1
n= Number of moles = 1
T= Standard temperature = 273 K
P= Standard pressure = 1 atm = 1.013 × 105 Nm-2
∴ V = nRT / P
= 1 x 8.314 x 273 / 1.013 x 105
= 0.0224 m3 = 22.4 litres
Hence, the molar volume of a gas at STP is 22.4 litres.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
The blades of a windmill sweep out a circle of area A. (a) If the wind flows at a velocity v perpendicular to the circle, what is the mass of the air passing through it in time t?(b) What is the kinetic energy of the air? (c) Assume that the windmill converts 25% of the wind's energy into electrical energy, and that A = 30 m2, v = 36 km/h and the density of air is 1.2 kg m-3. What is the electrical power produced?
Write in about 1000 words a fiction piece based on your speculation on the science and technology of the twenty-second century.
A monkey of mass 40 kg climbs on a rope (Fig. 5.20) which can stand a maximum tension of 600 N. In which of the following cases will the rope break: the monkey
(a) climbs up with an acceleration of 6 m s-2
(b) climbs down with an acceleration of 4 m s-2
(c) climbs up with a uniform speed of 5 m s-1
(d) falls down the rope nearly freely under gravity?
(Ignore the mass of the rope).
For the travelling harmonic wave
y (x, t) = 2.0 cos 2π (10t - 0.0080 x + 0.35)
Where x and y are in cm and t in s. Calculate the phase difference between oscillatory motion of two points separated by a distance of
(a) 4 m,
(b) 0.5 m,
(c) λ / 2 ,
(d) 3λ / 4
A famous relation in physics relates 'moving mass' m to the 'rest mass' m0 of a particle in terms of its speed v and the speed of light, c. (This relation first arose as a consequence of special relativity due to Albert Einstein). A boy recalls the relation almost correctly but forgets where to put the constant c. He writes:
m = m0 / (1-v2)½
A man walking briskly in rain with speed v must slant his umbrella forward making an angle θ with the vertical. A student derives the following relation between θ and v : tan θ = v and checks that the relation has a correct limit: as v → 0, θ →0, as expected. (We are assuming there is no strong wind and that the rain falls vertically for a stationary man). Do you think this relation can be correct ? If not, guess the correct relation.
Read each statement below carefully and state, with reasons and examples, if it is true or false:
A scalar quantity is one that
(a) is conserved in a process
(b) can never take negative values
(c) must be dimensionless
(d) does not vary from one point to another in space
(e) has the same value for observers with different orientations of axes
Does it matter if one uses gauge instead of absolute pressures in applying Bernoulli's equation? Explain.
In deriving Bernoulli's equation, we equated the work done on the fluid in the tube to its change in the potential and kinetic energy. (a) What is the largest average velocity of blood flow in an artery of diameter 2 x 10-3 m if the flow must remain laminar? (b) Do the dissipative forces become more important as the fluid velocity increases? Discuss qualitatively.