Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
The ideal gas equation relating pressure (P), volume (V), and absolute temperature (T) is given as:
PV= nRT
Where, R is the universal gas constant = 8.314 J mol-1K-1
n= Number of moles = 1
T= Standard temperature = 273 K
P= Standard pressure = 1 atm = 1.013 × 105 Nm-2
∴ V = nRT / P
= 1 x 8.314 x 273 / 1.013 x 105
= 0.0224 m3 = 22.4 litres
Hence, the molar volume of a gas at STP is 22.4 litres.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
The mass of a box measured by a grocer's balance is 2.300 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is
(a) the total mass of the box,
(b) the difference in the masses of the pieces to correct significant figures?
What amount of heat must be supplied to 2.0 x 10-2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure? (Molecular mass of N2 = 28; R = 8.3 J mol-1 K-1.)
Which of the following functions of time represent (a) simple harmonic, (b) periodic but not simple harmonic, and (c) non-periodic motion? Give period for each case of periodic motion (ω is any positive constant):
(a) sin ωt - cos wt
(b) sin3 ωt
(c) 3 cos (π/4 - 2ωt)
(d) cos ωt + cos 3ωt + cos 5ωt
(e) exp (-ω2t2)
A spring having with a spring constant 1200 N m-1 is mounted on a horizontal table as shown in Fig. A mass of 3 kg is attached to the free end of the spring. The mass is then pulled sideways to a distance of 2.0 cm and released.
Determine (i) the frequency of oscillations, (ii) maximum acceleration of the mass, and (iii) the maximum speed of the mass.
A person trying to lose weight (dieter) lifts a 10 kg mass, one thousand times, to a height of 0.5 m each time. Assume that the potential energy lost each time she lowers the mass is dissipated. (a) How much work does she do against the gravitational force? (b) Fat supplies 3.8 x 107 J of energy per kilogram which is converted to mechanical energy with a 20% efficiency rate. How much fat will the dieter use up?
The nearest star to our solar system is 4.29 light years away. How much is this distance in terms of parsecs? How much parallax would this star (named Alpha Centauri) show when viewed from two locations of the Earth six months apart in its orbit around the Sun?
A calorie is a unit of heat or energy and it equals about 4.2 J where 1J = 1 kg m2s–2. Suppose we employ a system of units in which the unit of mass equals α kg, the unit of length equals β m, the unit of time is γ s. Show that a calorie has a magnitude 4.2 α–1 β– 2 γ2 in terms of the new units.
A train runs along an unbanked circular track of radius 30 m at a speed of 54 km/h. The mass of the train is 106 kg. What provides the centripetal force required for this purpose - The engine or the rails? What is the angle of banking required to prevent wearing out of the rail?
When the planet Jupiter is at a distance of 824.7 million kilometers from the Earth, its angular diameter is measured to be 35.72" of arc. Calculate the diameter of Jupiter.
A bolt of mass 0.3 kg falls from the ceiling of an elevator moving down with an uniform speed of 7 m s-1. It hits the floor of the elevator (length of the elevator = 3 m) and does not rebound. What is the heat produced by the impact? Would your answer be different if the elevator were stationary?