Question 2

Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.

Answer

The ideal gas equation relating pressure (P), volume (V), and absolute temperature (T) is given as:

PV= nRT

Where, R is the universal gas constant = 8.314 J mol-1K-1

n= Number of moles = 1

T= Standard temperature = 273 K

P= Standard pressure = 1 atm = 1.013 × 105 Nm-2

∴  V  =  nRT / P

= 1 x 8.314 x 273  /  1.013 x 105

= 0.0224 m3 = 22.4 litres

Hence, the molar volume of a gas at STP is 22.4 litres.

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