From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Rate of diffusion of hydrogen, R1 = 28.7 cm3s-1
Rate of diffusion of another gas, R2= 7.2 cm3s-1
According to Graham's Law of diffusion, we have:
R1 / R2 = Underroot M2/M1
Where, M1 is the molecular mass of hydrogen = 2.020 g
M2 is the molecular mass of the unknown gas
∴ M2 =M1 (R1 / R2)2
=2.02 (28.7 / 7.2)2
= 32.09 g
32 g is the molecular mass of oxygen. Hence, the unknown gas is oxygen.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
( i ) The time period of a body having simple harmonic motion depends on the mass m of the body and the force constant k:
T =2π √m/k
A simple pendulum exhibits simple harmonic motion. Then why does the time period of a pendulum not depend upon its mass?
( ii ) For small angle oscillations, a simple pendulum exhibits simple harmonic motion ( more or less). For larger angles of oscillation, detailed analysis show that T is greater than 2π√ l/g. Explain.
( iii ) A boy with a wristwatch on his hand jumps from a helicopter. Will the wrist watch give the correct time during free fall?
( iv ) Find the frequency of oscillation of a simple pendulum that is free falling from a tall bridge.
A metre-long tube open at one end, with a movable piston at the other end, shows resonance with a fixed frequency source (a tuning fork of frequency 340 Hz) when the tube length is 25.5 cm or 79.3 cm. Estimate the speed of sound in air at the temperature of the experiment. The edge effects may be neglected.
A LASER is a source of very intense, monochromatic, and unidirectional beam of light. These properties of a laser light can be exploited to measure long distances. The distance of the Moon from the Earth has been already determined very precisely using a laser as a source of light. A laser light beamed at the Moon takes 2.56 s to return after reflection at the Moon's surface. How much is the radius of the lunar orbit around the Earth?
A man walking briskly in rain with speed v must slant his umbrella forward making an angle θ with the vertical. A student derives the following relation between θ and v : tan θ = v and checks that the relation has a correct limit: as v → 0, θ →0, as expected. (We are assuming there is no strong wind and that the rain falls vertically for a stationary man). Do you think this relation can be correct ? If not, guess the correct relation.
Just as precise measurements are necessary in science, it is equally important to be able to make rough estimates of quantities using rudimentary ideas and common observations. Think of ways by which you can estimate the following (where an estimate is difficult to obtain, try to get an upper bound on the quantity):
(a) the total mass of rain-bearing clouds over India during the Monsoon
(b) the mass of an elephant
(c) the wind speed during a storm
(d) the number of strands of hair on your head
(e) the number of air molecules in your classroom.
A solid cylinder of mass 20 kg rotates about its axis with angular speed 100 rad s-1. The radius of the cylinder is 0.25 m. What is the kinetic energy associated with the rotation of the cylinder? What is the magnitude of angular momentum of the cylinder about its axis?
A train, standing at the outer signal of a railway station blows a whistle of frequency 400 Hz in still air.
(i) What is the frequency of the whistle for a platform observer when the train
(a) approaches the platform with a speed of 10 m s-1,
(b) recedes from the platform with a speed of 10 m s-1?
(ii) What is the speed of sound in each case? The speed of sound in still air can be taken as 340 m s-1.
Attempt to formulate your ‘moral’ views on the practice of science. Imagine yourself stumbling upon a discovery, which has great academic interest but is certain to have nothing but dangerous consequences for the human society. How, if at all, will you resolve your dilemma?
Choose the correct alternative:
(a) If the zero of potential energy is at infinity, the total energy of an orbiting satellite is negative of its kinetic/potential energy.
(b) The energy required to launch an orbiting satellite out of earth’s gravitational influence is more/less than the energy required to project a stationary object at the same height (as the satellite) out of earth’s influence.
You have learnt that a travelling wave in one dimension is represented by a function y = f (x, t) where x and t must appear in the combination x - v t or x + v t, i.e. y = f (x ± v t). Is the converse true? Examine if the following functions for y can possibly represent a travelling wave:
(a) ( x - v t )2
(b) log [ x + vt / x0]
(c) 1 / (x + vt)