Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Volume of the room, V= 25.0 m3
Temperature of the room, T= 27°C = 300 K
Pressure in the room, P= 1 atm = 1 × 1.013 × 105 Pa
The ideal gas equation relating pressure (P), Volume (V), and absolute temperature (T) can be written as:
PV = kBNT
Where, KB is Boltzmann constant = 1.38 × 10-23 m2 kg s-2K-1
N is the number of air molecules in the room
∴ N = PV / KB T
= 1.013 x 105 x 25 / 1.38 x 10-23 x 300
= 6.11 × 1026 molecules
Therefore, the total number of air molecules in the given room is 6.11 × 1026.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
Toricelli's barometer used mercury. Pascal duplicated it using French wine of density 984 kg m-3. Determine the height of the wine column for normal atmospheric pressure.
A man can swim with a speed of 4.0 km/h in still water. How long does he take to cross a river 1.0 km wide if the river flows steadily at 3.0 km/h and he makes his strokes normal to the river current? How far down the river does he go when he reaches the other bank?
Figure 3.25 gives a speed-time graph of a particle in motion along a constant direction. Three equal intervals of time are shown. In which interval is the average acceleration greatest in magnitude? In which interval is the average speed greatest? Choosing the positive direction as the constant direction of motion, give the signs of v and a in the three intervals. What are the accelerations at the points A, B, C and D?
A boy standing on a stationary lift (open from above) throws a ball upwards with the maximum initial speed he can, equal to 49 m/s. How much time does the ball take to return to his hands? If the lift starts moving up with a uniform speed of 5 m/s and the boy again throws the ball up with the maximum speed he can, how long does the ball take to return to his hands?
Suggest a suitable physical situation for each of the following graphs (Fig 3.22):
(a)
(Figure 3.22)
A train runs along an unbanked circular track of radius 30 m at a speed of 54 km/h. The mass of the train is 106 kg. What provides the centripetal force required for this purpose - The engine or the rails? What is the angle of banking required to prevent wearing out of the rail?
The industrial revolution in England and Western Europe more than two centuries ago was triggered by some key scientific and technological advances. What were these advances ?
A constant force acting on a body of mass 3.0 kg changes its speed from 2.0 m s–1 to 3.5 m s–1 in 25 s. The direction of the motion of the body remains unchanged. What is the magnitude and direction of the force?
A hospital uses an ultrasonic scanner to locate tumours in a tissue. What is the wavelength of sound in the tissue in which the speed of sound is 1.7 km s-1? The operating frequency of the scanner is 4.2 MHz.
Which of the following relationships between the acceleration a and the displacement x of a particle involve simple harmonic motion?
(a) a = 0.7x
(b) a = -200x2
(c) a = -10x
(d) a = 100x3