Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Volume of the room, V= 25.0 m3
Temperature of the room, T= 27°C = 300 K
Pressure in the room, P= 1 atm = 1 × 1.013 × 105 Pa
The ideal gas equation relating pressure (P), Volume (V), and absolute temperature (T) can be written as:
PV = kBNT
Where, KB is Boltzmann constant = 1.38 × 10-23 m2 kg s-2K-1
N is the number of air molecules in the room
∴ N = PV / KB T
= 1.013 x 105 x 25 / 1.38 x 10-23 x 300
= 6.11 × 1026 molecules
Therefore, the total number of air molecules in the given room is 6.11 × 1026.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
A block of mass 25 kg is raised by a 50 kg man in two different ways as shown in Fig. 5.19. What is the action on the floor by the man in the two cases? If the floor yields to a normal force of 700 N, which mode should the man adopt to lift the block without the floor yielding?
Can Bernoulli's equation be used to describe the flow of water through a rapid in a river? Explain.
A cyclist starts from the centre O of a circular park of radius 1 km, reaches the edge P of the park, then cycles along the circumference, and returns to the centre along QO as shown in Fig. 4.21. If the round trip takes 10 min, what is the
(a) net displacement,
(b) average velocity, and
(c) average speed of the cyclist?
In a harbour, wind is blowing at the speed of 72 km/h and the flag on the mast of a boat anchored in the harbour flutters along the N-E direction. If the boat starts moving at a speed of 51 km/h to the north, what is the direction of the flag on the mast of the boat?
The length, breadth and thickness of a rectangular sheet of metal are 4.234 m, 1.005 m, and 2.01 cm respectively. Give the area and volume of the sheet to correct significant figures.
( i ) The time period of a body having simple harmonic motion depends on the mass m of the body and the force constant k:
T =2π √m/k
A simple pendulum exhibits simple harmonic motion. Then why does the time period of a pendulum not depend upon its mass?
( ii ) For small angle oscillations, a simple pendulum exhibits simple harmonic motion ( more or less). For larger angles of oscillation, detailed analysis show that T is greater than 2π√ l/g. Explain.
( iii ) A boy with a wristwatch on his hand jumps from a helicopter. Will the wrist watch give the correct time during free fall?
( iv ) Find the frequency of oscillation of a simple pendulum that is free falling from a tall bridge.
A metre-long tube open at one end, with a movable piston at the other end, shows resonance with a fixed frequency source (a tuning fork of frequency 340 Hz) when the tube length is 25.5 cm or 79.3 cm. Estimate the speed of sound in air at the temperature of the experiment. The edge effects may be neglected.
A LASER is a source of very intense, monochromatic, and unidirectional beam of light. These properties of a laser light can be exploited to measure long distances. The distance of the Moon from the Earth has been already determined very precisely using a laser as a source of light. A laser light beamed at the Moon takes 2.56 s to return after reflection at the Moon's surface. How much is the radius of the lunar orbit around the Earth?
A man walking briskly in rain with speed v must slant his umbrella forward making an angle θ with the vertical. A student derives the following relation between θ and v : tan θ = v and checks that the relation has a correct limit: as v → 0, θ →0, as expected. (We are assuming there is no strong wind and that the rain falls vertically for a stationary man). Do you think this relation can be correct ? If not, guess the correct relation.
Just as precise measurements are necessary in science, it is equally important to be able to make rough estimates of quantities using rudimentary ideas and common observations. Think of ways by which you can estimate the following (where an estimate is difficult to obtain, try to get an upper bound on the quantity):
(a) the total mass of rain-bearing clouds over India during the Monsoon
(b) the mass of an elephant
(c) the wind speed during a storm
(d) the number of strands of hair on your head
(e) the number of air molecules in your classroom.