Three vessels of equal capacity have gases at the same temperature and pressure. The first vessel contains neon (monatomic), the second contains chlorine (diatomic), and the third contains uranium hexafluoride (polyatomic). Do the vessels contain equal number of respective molecules? Is the root mean square speed of molecules the same in the three cases? If not, in which case is vrmsthe largest?
Yes.All contain the same number of the respective molecules.
No. The root mean square speed of neon is the largest.
Since the three vessels have the same capacity, they have the same volume.
Hence, each gas has the same pressure, volume, and temperature.
According to Avogadro's law, the three vessels will contain an equal number of the respective molecules. This number is equal to Avogadro's number, N= 6.023 × 1023.
The root mean square speed (vrms) of a gas of mass m, and temperature T, is given by the relation:
vrms = underroot 3kT / m
Where, k is Boltzmann constant
For the given gases, k and T are constants.
Hence vrmsdepends only on the mass of the atoms, i.e.,
vrms ∝ underroot 1/m
Therefore, the root mean square speed of the molecules in the three cases is not the same. Among neon, chlorine, and uranium hexafluoride, the mass of neon is the smallest. Hence, neon has the largest root mean square speed among the given gases.
Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.
Estimate the average thermal energy of a helium atom at
(i) room temperature (27 °C),
(ii) the temperature on the surface of the Sun (6000 K),
(iii) the temperature of 10 million Kelvin (the typical core temperature in the case of a star).
An air bubble of volume 1.0 cm3 rises from the bottom of a lake 40 m deep at a temperature of 12 °C. To what volume does it grow when it reaches the surface, which is at a temperature of 35 °C?
Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3Å.
A metre long narrow bore held horizontally (and closed at one end) contains a 76 cm long mercury thread, which traps a 15 cm column of air. What happens if the tube is held vertically with the open end at the bottom?
Molar volume is the volume occupied by 1 mol of any (ideal) gas at standard temperature and pressure (STP: 1 atmospheric pressure, 0 °C). Show that it is 22.4 litres.
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3s-1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3s-1. Identify the gas.
[Hint:Use Graham's law of diffusion: R1/R2= (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
Some of the most profound statements on the nature of science have come from Albert Einstein, one of the greatest scientists of all time. What do you think did Einstein mean when he said : “The most incomprehensible thing about the world is that it is comprehensible”?
The sign of work done by a force on a body is important to understand. State carefully if the following quantities are positive or negative:
(a) work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket.
(b) work done by gravitational force in the above case,
(c) work done by friction on a body sliding down an inclined plane,
(d) work done by an applied force on a body moving on a rough horizontal plane with uniform velocity,
(e) work done by the resistive force of air on a vibrating pendulum in bringing it to rest.
A geyser heats water flowing at the rate of 3.0 litres per minute from 27 °C to 77 °C. If the geyser operates on a gas burner, what is the rate of consumption of the fuel if its heat of combustion is 4.0 x 104 J/g?
In deriving Bernoulli's equation, we equated the work done on the fluid in the tube to its change in the potential and kinetic energy. (a) What is the largest average velocity of blood flow in an artery of diameter 2 x 10-3 m if the flow must remain laminar? (b) Do the dissipative forces become more important as the fluid velocity increases? Discuss qualitatively.
A metre-long tube open at one end, with a movable piston at the other end, shows resonance with a fixed frequency source (a tuning fork of frequency 340 Hz) when the tube length is 25.5 cm or 79.3 cm. Estimate the speed of sound in air at the temperature of the experiment. The edge effects may be neglected.
A train runs along an unbanked circular track of radius 30 m at a speed of 54 km/h. The mass of the train is 106 kg. What provides the centripetal force required for this purpose - The engine or the rails? What is the angle of banking required to prevent wearing out of the rail?
Attempt to formulate your ‘moral’ views on the practice of science. Imagine yourself stumbling upon a discovery, which has great academic interest but is certain to have nothing but dangerous consequences for the human society. How, if at all, will you resolve your dilemma?
Science, like any knowledge, can be put to good or bad use, depending on the user. Given below are some of the applications of science. Formulate your views on whether the particular application is good, bad or something that cannot be so clearly categorised :
(a) Mass vaccination against small pox to curb and finally eradicate this disease from the population. (This has already been successfully done in India).
(b) Television for eradication of illiteracy and for mass communication of news and ideas.
(c) Prenatal sex determination
(d) Computers for increase in work efficiency
(e) Putting artificial satellites into orbits around the Earth
(f ) Development of nuclear weapons
(g) Development of new and powerful techniques of chemical and biological warfare).
(h) Purification of water for drinking
(i) Plastic surgery
(j ) Cloning
The driver of a three-wheeler moving with a speed of 36 km/h sees a child standing in the middle of the road and brings his vehicle to rest in 4.0 s just in time to save the child. What is the average retarding force on the vehicle? The mass of the three-wheeler is 400 kg and the mass of the driver is 65 kg.
A drunkard walking in a narrow lane takes 5 steps forward and 3 steps backward, followed again by 5 steps forward and 3 steps backward, and so on. Each step is 1 m long and requires 1 s. Plot the x-t graph of his motion. Determine graphically and otherwise how long the drunkard takes to fall in a pit 13 m away from the start.
Can you associate vectors with (a) the length of a wire bent into a loop, (b) a plane area, (c) a sphere? Explain.
A travelling harmonic wave on a string is described by
y(x,t) = 7.5sin [0.0050x + 12t + π/4]
(a) What are the displacement and velocity of oscillation of a point at x = 1 cm, and t = 1 s? Is this velocity equal to the velocity of wave propagation?
(b) Locate the points of the string which have the same transverse displacements and velocity as the x = 1 cm point at t = 2 s, 5 s and 11 s.
Two vessels have the same base area but different shapes. The first vessel takes twice the volume of water that the second vessel requires to fill upto a particular common height. Is the force exerted by the water on the base of the vessel the same in the two cases? If so, why do the vessels filled with water to that same height give different readings on a weighing scale?