Which hybrid orbitals are used by carbon atoms in the following molecules?
(a)CH3–CH3;
(b) CH3–CH=CH2;
(c) CH3-CH2-OH;
(d) CH3-CHO
(e) CH3COOH
Hybrid orbital are formed by the overlapping of orbitals having almost same energy.
Single bond= one sigma bond = sp3 hybridization
Double bond = one sigma bond + one pie bond = sp2 hybridization
Triple bond = one sigma bond + two pie bond = sp hybridization
(a)
According to structure, C1 & C2 are making 4 sigma bonds(single bond) each with the help of one s hybrid orbital & 3 p hybrid orbital, hence C1& C2 are sp3 hybridised
(b)
Here C1 is making 4 sigma bond therefore it s sp3 hybridised , while C2 and C3 are making a double bond( 1 sigma + 1 pie bond ) therefore they both are sp2 hybridized.
(c)
Both the carbons C1 & C2 are making single bond(sigma bond),therefore they are sp3hybridized.
(d)
From the structure it is clear that C1 is making sigma bonds only, therefore it is sp3 hybridised.C2 is making a double bond therefore it is sp2 hybridised.
C1 is sp3 hybridized and C2 is sp2 hybridized.
(e)
Here C1 is making a sigma bond therefore it is in sp3 hybridization state, while C2 is making a double bond ,it is in sp2 hybridised state.
Calculate the amount of carbon dioxide that could be produced when
(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.
The mass of an electron is 9.1 × 10–31 kg. If its K.E. is 3.0 × 10–25 J, calculate its wavelength.
Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Balance the following redox reactions by ion – electron method :
(a) MnO4 – (aq) + I – (aq) → MnO2 (s) + I2(s) (in basic medium)
(b) MnO4 – (aq) + SO2 (g) → Mn2+ (aq) + HSO4– (aq) (in acidic solution)
(c) H2O2 (aq) + Fe 2+ (aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d) Cr2O7 2– + SO2(g) → Cr3+ (aq) + SO42– (aq) (in acidic solution)
In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the system. What is the change in internal energy for the process?
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
In a reaction A + B2 → AB2 Identify the limiting reagent, if any, in the following reaction mixtures.
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide?
Which one of the following will have largest number of atoms?
(i) 1 g Au (s)
(ii) 1 g Na (s)
(iii) 1 g Li (s)
(iv) 1 g of Cl2(g)
Density of a gas is found to be 5.46 g/dm3 at 27 °C at 2 bar pressure. What will be its density at STP?
Write chemical equations for combustion reaction of the following hydrocarbons:
(i) Butane
(ii) Pentene
(iii) Hexyne
(iv) Toluene
Chlorine is prepared in the laboratory by treating manganese dioxide (MnO2) with aqueous hydrochloric acid according to the reaction
4HCl(aq) + MnO2(s) → 2H2O(l) + MnCl2(aq) + Cl2(g)
How many grams of HCl react with 5.0 g of manganese dioxide?
Explain why cations are smaller and anions larger in radii than their parent atoms?
The concentration of hydrogen ion in a sample of soft drink is 3.8 × 10–3 M. what is its pH?
What is meant by the term bond order? Calculate the bond order of: N2, O2,O2+,and O2-.
Draw diagrams showing the formation of a double bond and a triple bond between carbon atoms in C2H4 and C2H2 molecules.
If ten volumes of dihydrogen gas react with five volumes of dioxygen gas, how many volumes of water vapour would be produced?
Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
Describe the structure of the common form of ice.
myself whore sharma like vary nice answer
Well explained
Very well explained
Well explained
thnq so much
Thanks
Thanks